In today's Spotlight we take a look at a specific example of the challenges researchers face in improving fuel cell technology and the important role that modern laboratory instruments such as electron microscopes play in their work. Fuel cells have gained a lot of attention because they provide a potential solution to our addiction to fossil fuels. Energy production from oil, coal and gas is an extremely polluting, not to mention wasteful, process that consists of heat extraction from fuel by burning it, conversion of that heat to mechanical energy, and transformation of that mechanical energy into electrical energy. In contrast, fuel cells are electrochemical devices that convert a fuel's chemical energy directly to electrical energy with high efficiency and without combustion (although fuel cells operate similar to batteries, an important difference is that batteries store energy, while fuel cells can produce electricity continuously as long as fuel and air are supplied).
The field of printable electronics is already well established. The biggest limitation to further increasing the functionality of printed electronics devices is energy management, i.e. the space requirement and cost of batteries. Ideally, power and energy storage devices will be integrated into the manufacturing process to be printed at the same time. What is still needed to complement a further deveopment of printed electronics device technology are truly printable charge storage devices that can be easily fabricated using large-scale, solution-based, roll-to-roll processing, while still displaying good electrochemical performance. Only fully printable charge storage devices would allow for full integration into the manufacturing process of printed electronics.
New work by this Canadian research team has now demonstrated that it is possible to significantly increase the catalytic site density of iron-based non-precious metal catalysts (NPMCs) to levels that were not thought possible before. The problem that this work resolves is that of the low activity of NPMCs compared to platinum-based catalysts. The best of these new NPMCs is more than 30 times more active compared to the previous best reported activity for NPMCs, and about 100 times more active than the majority of other NPMCs. Furthermore, their activity has reached about 1/10th the volumetric activity of state-of-the-art platinum-based catalysts (about 50 wt% platinum on carbon), which is the 2010 NPMC activity target set by the U.S. Department of Energy.
Platinum nanoparticles are widely used as the cathode material in hydrogen/oxygen fuel cells due to their efficiency in catalyzing the oxygen reduction reaction (ORR), the process that breaks the bonds of the oxygen molecules. Although platinum is still considered the state-of-the-art ORR catalyst, it does not exhibit good stability. Typically, catalyst performance degradation begins as soon as the catalyst is introduced into a fuel cell and continues until it is no longer active. Platinum can lose its effectiveness either by clumping together or by becoming 'poisoned' by carbon monoxide, requiring high hydrogen purity or higher catalyst densities for the fuel cell to stay effective. This, together with the high cost of platinum is seen as one of the major showstoppers to producing mass market fuel cells for commercial applications. Researchers now found that vertically-aligned nitrogen-containing carbon nanotubes could be used as effective ORR electrocatalysts.
The hydrogen that will power tomorrow's cars is not a naturally occurring resource that can be tapped by drilling a hole in the ground. Hydrogen has to be produced, and that can be done using a variety of resources. The cleanest by far of course would be renewable energy electrolysis: using electricity to split water into hydrogen and oxygen; this electricity could be generated using renewable energy technologies such as wind, solar, geo- and hydrothermal power. As it stands, most of today's hydrogen production is 'dirty' - it is produced from methane in natural gas using high-temperature steam in what is called steam methane reforming. Many research groups around the world are working hard on developing cheap, clean and efficient technologies to produce hydrogen from water, particularly using sunlight (artificial photosynthesis). This would be the ultimate clean, renewable and abundant energy source. However, to become commercially viable, fuel cells have to overcome the barrier of high catalyst cost caused by the exclusive use of expensive platinum and platinum-based catalysts in the fuel-cell electrodes - the reason is that platinum is the most efficient electrocatalyst for accelerating chemical reactions in fuel cells. Scientists have found that platinum catalysts can be replaced with bacteria-produced hydrogenase enzymes that have nickel and iron in their active sites.
Modern fuel cells have the potential to revolutionize transportation. Like battery-electric vehicles, fuel cell vehicles are propelled by electric motors. But while battery electric vehicles use electricity from an external source and store it in a battery, fuel cells onboard a vehicle are electrochemical devices that convert a fuel's chemical energy directly to electrical energy with high efficiency and without combustion. One of the leading fuel cell technologies developed, in particular for transportation applications, is the proton exchange membrane (PEM) fuel cell, also known as polymer electrolyte membrane fuel cells - both resulting in the same acronym PEMFC. These fuel cells are powered by the electrochemical oxidation reaction of hydrogen and by the electroreduction of the oxygen contained in air. Presently, platinum-based electrocatalysts are the most widely used in PEM fuel cell prototypes. However, this metal is expensive due to its limited supply and its price is highly volatile. This creates one of the major barriers preventing commercialization of PEMFCs - the lack of suitable materials to make them affordable. Nanotechnology provides solutions to this problem.
Nanotechnology applications could provide decisive technological breakthroughs in the energy sector and have a considerable impact on creating the sustainable energy supply that is required to make the transition from fossil fuels. Possibilities range from gradual short- and medium-term improvements for a more efficient use of conventional and renewable energy sources all the way to completely new long-term approaches for energy recovery and utilization. With enough political will - and funding - nanotechnology could make essential contributions to sustainable energy supply and global climate protection policies. The technological foundation is there, all it takes is political leadership to create the right research and investment conditions to make it happen.
Storing the fuel that is needed to run a hydrogen car in a compact and affordable way is still a major challenge. You would need about 5 kg of hydrogen to have the same average driving range as today's cars. Since hydrogen's density is only 1/10th of a gram per liter at room temperature, that means you somehow need to pack 50,000 liters of hydrogen into your tank. There are three ways of doing this: as a high-pressure compressed gas; a cryogenic liquid; or as a solid. Rather than using hundreds of atmospheres to compress hydrogen into a tank, or cooling it down to minus 252 C to liquefy it, hydrogen storage in solid form offers the safest alternative for transportation and storage of hydrogen. Research in this area has led to metal hydrides, chemical hydrides, and physisorption-based storage, where hydrogen is adsorbed onto the interior surfaces of a porous material. The stored hydrogen can then be released by heat, electricity, or chemical reaction. Many metals are capable of absorbing hydrogen as well. The storage of gas in solids is not only an intriguing alternative for hydrogen storage but other types of gases, such as carbon dioxide and other environmentally important gases as well. Gas storage in solids is quickly becoming an important technology, with applications ranging from energy and the environment to biology and medicine. A new review article describes the types of material that make good porous gas storage materials, why different porous solids are good for the storage of different gases, and what criteria need to be met to make a useable gas storage material.